ステアリン酸カルシウム


Calcium stearate/ja

ステアリン酸カルシウムCalcium stearate)は、カルシウムカルボン酸塩で、カルシウム石鹸に分類される。この塩はいくつかの潤滑剤界面活性剤、また多くの食品の成分である。 白い蝋状の粉末である。

Calcium stearate/ja
Names
Preferred IUPAC name
Calcium di(octadecanoate)
Other names
E470
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
UNII
Properties
C36H70CaO4
Molar mass 607.030 g·mol−1
Appearance white to yellowish-white powder
Density 1.08 g/cm3
Melting point 155 °C (311 °F; 428 K)
0.004 g/100 mL (15 °C)
Solubility soluble in hot pyridine
slightly soluble in oil
insoluble in alcohol, ether
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
1
0

生産と発生

ステアリン酸カルシウムはステアリン酸酸化カルシウムを加熱することによって生成される:

2 C17H35COOH + CaO → (C17H35COO)2Ca + H2O

ステアリン酸カルシウムは石鹸カスの主成分でもあり、石鹸を硬水と混ぜたときにできる白い固体である。 ナトリウムやカリウムを含む石鹸とは異なり、ステアリン酸カルシウムは水に溶けず、泡立ちが悪い。 商業的には水に50%分散させたもの、またはスプレードライの粉末として販売されている。 食品添加物としては、一般的なE番号 E470で知られている。

Applications

Calcium stearate is a waxy material with low solubility in water, unlike traditional sodium and potassium soaps. It is also easy and cheap to produce, and exhibits low toxicity. These attributes are the basis of many of its applications. Related applications exist for the magnesium stearate.

  • Calcium stearate is used as a flow agent and surface conditioner in some candies such as Smarties, jawbreakers and Sprees.
  • It is a waterproofing agent for fabrics.
  • A lubricant in pencils and crayons.
  • A lubricant in the dry drawing method of wire production
  • The concrete industry uses calcium stearate for efflorescence control of cementitious products used in the production of concrete masonry units i.e. paver and block, as well as waterproofing.
  • In paper production, calcium stearate is used as a lubricant to provide good gloss, preventing dusting and fold cracking in paper and paperboard making.
  • In plastics, it can act as an acid scavenger or neutralizer at concentrations up to 1000ppm, a lubricant and a release agent. It may be used in plastic colorant concentrates to improve pigment wetting. In rigid PVC, it can accelerate fusion, improve flow, and reduce die swell.
  • Applications in the personal care and pharmaceutical industry include tablet mold release, anti-tack agent, and gelling agent.
  • Calcium stearate is a component in some types of defoamers.
  • Anticaking agent for drugs etc.