Fatty acid: Difference between revisions

Line 150: Line 150:
!Lipid numbers
!Lipid numbers
|18:3<br />[[α-Linolenic acid|18:3n3]]<br />[[α-Linolenic acid|18:3,&nbsp;''cis'',''cis'',''cis''-Δ<sup>9</sup>,Δ<sup>12</sup>,Δ<sup>15</sup>]]<br />[[α-Linolenic acid|18:3(9,12,15)]]
|18:3<br />[[α-Linolenic acid|18:3n3]]<br />[[α-Linolenic acid|18:3,&nbsp;''cis'',''cis'',''cis''-Δ<sup>9</sup>,Δ<sup>12</sup>,Δ<sup>15</sup>]]<br />[[α-Linolenic acid|18:3(9,12,15)]]
|'''Lipid numbers''' take the form ''C'':''D'',{{efn|name=c:d}} where ''C'' is the number of carbon atoms in the fatty acid and ''D'' is the number of double bonds in the fatty acid. If D is more than one, the double bonds are assumed to be interrupted by [[methylene bridge|{{chem|CH|2}} units]], ''i.e.'', at intervals of 3 carbon atoms along the chain. For instance, [[α-Linolenic acid|α-linolenic acid]] is an 18:3 fatty acid and its three double bonds are located at positions Δ<sup>9</sup>, Δ<sup>12</sup>, and Δ<sup>15</sup>. This notation can be ambiguous, as some different fatty acids can have the same ''C'':''D'' numbers. Consequently, when ambiguity exists this notation is usually paired with either a Δ<sup>''x''</sup> or ''n''−''x'' term. For instance, although [[α-Linolenic acid|α-linolenic acid]] and [[gamma-Linolenic acid|γ-linolenic acid]] are both 18:3, they may be unambiguously described as 18:3n3 and 18:3n6 fatty acids, respectively. For the same purpose, IUPAC recommends using a list of double bond positions in parentheses, appended to the C:D notation. For instance, IUPAC recommended notations for α- and γ-linolenic acid are 18:3(9,12,15) and 18:3(6,9,12), respectively.
|'''Lipid numbers''' take the form ''C'':''D'', where ''C'' is the number of carbon atoms in the fatty acid and ''D'' is the number of double bonds in the fatty acid. If D is more than one, the double bonds are assumed to be interrupted by [[methylene bridge|{{chem|CH|2}} units]], ''i.e.'', at intervals of 3 carbon atoms along the chain. For instance, [[α-Linolenic acid|α-linolenic acid]] is an 18:3 fatty acid and its three double bonds are located at positions Δ<sup>9</sup>, Δ<sup>12</sup>, and Δ<sup>15</sup>. This notation can be ambiguous, as some different fatty acids can have the same ''C'':''D'' numbers. Consequently, when ambiguity exists this notation is usually paired with either a Δ<sup>''x''</sup> or ''n''−''x'' term. For instance, although [[α-Linolenic acid|α-linolenic acid]] and [[gamma-Linolenic acid|γ-linolenic acid]] are both 18:3, they may be unambiguously described as 18:3n3 and 18:3n6 fatty acids, respectively. For the same purpose, IUPAC recommends using a list of double bond positions in parentheses, appended to the C:D notation. For instance, IUPAC recommended notations for α- and γ-linolenic acid are 18:3(9,12,15) and 18:3(6,9,12), respectively.
|}
|}