Translations:Zinc/22/en: Difference between revisions

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Message definition (Zinc)
Zinc chemistry is similar to the chemistry of the late first-row transition metals, [[nickel]] and copper, though it has a filled d-shell and compounds are [[diamagnetic]] and mostly colorless. The [[ionic radii]] of zinc and magnesium happen to be nearly identical. Because of this some of the equivalent salts have the same [[crystal structure]], and in other circumstances where ionic radius is a determining factor, the chemistry of zinc has much in common with that of magnesium. In other respects, there is little similarity with the late first-row transition metals. Zinc tends to form bonds with a greater degree of [[covalency]] and much more stable [[Complex (chemistry)|complexes]] with [[nitrogen|N]]- and [[sulfur|S]]- donors. Complexes of zinc are mostly 4- or 6- [[coordinate covalent bond|coordinate]], although 5-coordinate complexes are known.

Zinc chemistry is similar to the chemistry of the late first-row transition metals, nickel and copper, though it has a filled d-shell and compounds are diamagnetic and mostly colorless. The ionic radii of zinc and magnesium happen to be nearly identical. Because of this some of the equivalent salts have the same crystal structure, and in other circumstances where ionic radius is a determining factor, the chemistry of zinc has much in common with that of magnesium. In other respects, there is little similarity with the late first-row transition metals. Zinc tends to form bonds with a greater degree of covalency and much more stable complexes with N- and S- donors. Complexes of zinc are mostly 4- or 6- coordinate, although 5-coordinate complexes are known.