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Found 2 translations.
Name | Current message text |
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h English (en) | Mechanisms 1 and 2 represent [[hydride]] gain, in which the molecule gains what amounts to be one hydride ion. Mechanisms 3 and 4 [[Radical (chemistry)|radical formation]] and hydride loss. Radical species contain unpaired electron atoms and are very chemically active. Hydride loss is the inverse process of the hydride gain seen before. The final two mechanisms show [[nucleophilic addition]] and a reaction using a carbon radical. {| |- |[[File:Hydride Transfer A.jpg|400px|thumb|left|Mechanism 1. Hydride transfer occurs by addition of H<sup>+</sup> and 2 e<sup>−</sup>]] |[[File:Hydride Transfer B.jpg|400px|thumb|right|Mechanism 2. Hydride transfer by abstraction of hydride from NADH]] |- |[[File:Radical Formation with FAD.jpg|400px|left|thumb|Mechanism 3. Radical formation by electron abstraction]] |[[File:Hydride Loss using FAD.jpg|400px|right|thumb|Mechanism 4. The loss of hydride to electron deficient R group]] |- |[[File:Nucleophilic Substitution using FAD.jpg|400px|left|thumb|Mechanism 5. Use of nucleophilic addition to break R<sub>1</sub>-R<sub>2</sub> bond]] |[[File:Radical Reaction with FAD.jpg|400px|right|thumb|Mechanism 6. Carbon radical reacts with O<sub>2</sub> and acid to form H<sub>2</sub>O<sub>2</sub>]] |} {{clear}} |
h Japanese (ja) | メカニズム1と2は[[hydride/ja|ヒドリド]]獲得を表し、分子は1つのヒドリドイオンとなるものを獲得する。メカニズム3と4は[[Radical (chemistry)/ja|ラジカル生成]]とヒドリド喪失を表す。ラジカル種は不対電子原子を含み、非常に化学的に活性である。ヒドリド損失は、前に見たヒドリド獲得の逆過程である。最後の2つの機構は、[[nucleophilic addition/ja|求核付加]]と炭素ラジカルを用いた反応である。 {| |- |[[File:Hydride Transfer A.jpg|400px|thumb|left|メカニズム1. 水素化物の移動はH<sup>+</sup>と2e<sup>-</sup>の付加によって起こる。]] |[[File:Hydride Transfer B.jpg|400px|thumb|right|メカニズム2. NADHからのヒドリドの脱離によるヒドリド移動]] |- |[[File:Radical Formation with FAD.jpg|400px|left|thumb|メカニズム3. 電子の脱離によるラジカル生成]] |[[File:Hydride Loss using FAD.jpg|400px|right|thumb|メカニズム4. 電子不足のR基へのヒドリドの損失]] |- |[[File:Nucleophilic Substitution using FAD.jpg|400px|left|thumb|メカニズム5. 求核付加を用いてR<sub>1</sub>-R<sub>2</sub>結合を切断する。]] |[[File:Radical Reaction with FAD.jpg|400px|right|thumb|メカニズム6. 炭素ラジカルがO<sub>2</sub>および酸と反応してH<sub>2</sub>O<sub>2</sub>を生成する。]] |} {{clear}} |