Lumisterol/ja - Revision history

Fire: Created page with "Category:Vitamin D Category:Sterols"

2024-04-13T05:51:51Z

Created page with "Category:Vitamin D Category:Sterols"

← Older revision		Revision as of 14:51, 13 April 2024
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	~~<div lang="en" dir="ltr" class="mw-content-ltr">~~		'''ルミステロール'''（'''Lumisterol'''）は、[[steroid/ja\|ステロイド]]化合物の[[vitamin D/ja\|ビタミンD]]ファミリーに属する化合物である。[[ergosterol/ja\|エルゴステロール]]の(9β,10α)[[stereoisomer/ja\|立体異性体]]であり、[[ergocalciferol/ja\|ビタミンD<sub>2</sub>]]とルミステロールの混合物であったビタミンD<sub>1</sub>の調製において光化学的副産物として生成された。ビタミンD<sub>2</sub>は、電気環式開環とそれに続く[[Sigmatropic reaction/ja#.5B1.2C7.5D_Shifts\|シグマトロピック[1,7]水素化物シフト]]によってルミステロールから生成することができる。
	'''Lumisterol''' ~~is a compound that is part of the~~ [[vitamin D]] ~~family of~~ [[~~steroid~~]] ~~compounds. It is the~~ (9β,10α) [[stereoisomer]] of [[~~ergosterol]] and was produced as a photochemical by-product in the preparation of vitamin D~~<sub>1</sub>~~, which was a mixture of [[Ergocalciferol\|vitamin D~~<sub>2</sub>~~]] and lumisterol. Vitamin D~~<sub>2</sub> ~~can be formed from lumisterol by an electrocyclic ring opening and subsequent~~ [[Sigmatropic reaction#.5B1.2C7.5D_Shifts\|~~sigmatropic~~ [1,7] ~~hydride shift~~]].

	~~Lumisterol has an analog based on~~ [[7-~~dehydrocholesterol~~]]~~, known as lumisterol 3.~~		ルミステロールには、ルミステロール3として知られる[[7-デヒドロコレステロール]]に基づく類似体がある。
	~~</div>~~


	~~<div lang="en" dir="ltr" class="mw-content-ltr">~~
	~~{{二次利用\|date=4 May 2023}}~~
	[[Category:Vitamin D]]		[[Category:Vitamin D]]
	[[Category:Sterols]]		[[Category:Sterols]]
	~~</div>~~

Fire: Created page with "{{chembox | Watchedfields = changed | verifiedrevid = 408754551 | Name = Lumisterol | ImageFile = Lumisterol.svg | ImageSize = 200px | ImageName = Lumisterol | IUPACName = (22''E'')-9β,10α-Ergosta-5,7,22-trien-3β-ol | SystematicName = (1''R'',3a''R'',7''S'',9a''S'',9b''R'',11a''R'')-1-[(2''R'',3''E'',5''R'')-5,6-Dimethylhept-3-en-2-yl]-9a,11a-dimethyl-2,3,3a,6,7,8,9,9a,9b,10,11,11a-dodecahydro-1''H''-cyclopenta[''a'']phenanthren-7-ol |Section1={{Chembox Identifiers |..."

2024-04-13T05:45:57Z

Created page with "{{chembox | Watchedfields = changed | verifiedrevid = 408754551 | Name = Lumisterol | ImageFile = Lumisterol.svg | ImageSize = 200px | ImageName = Lumisterol | IUPACName = (22''E'')-9β,10α-Ergosta-5,7,22-trien-3β-ol | SystematicName = (1''R'',3a''R'',7''S'',9a''S'',9b''R'',11a''R'')-1-[(2''R'',3''E'',5''R'')-5,6-Dimethylhept-3-en-2-yl]-9a,11a-dimethyl-2,3,3a,6,7,8,9,9a,9b,10,11,11a-dodecahydro-1''H''-cyclopenta[''a'']phenanthren-7-ol |Section1={{Chembox Identifiers |..."

← Older revision		Revision as of 14:45, 13 April 2024
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	<languages />		<languages />
	~~<div lang="en" dir="ltr" class="mw-content-ltr">~~
	{{chembox		{{chembox
	\| Watchedfields = changed		\| Watchedfields = changed
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	}}		}}
	~~</div>~~

	<div lang="en" dir="ltr" class="mw-content-ltr">		<div lang="en" dir="ltr" class="mw-content-ltr">

Fire: Created page with "ルミステロール"

2024-04-13T05:45:53Z

Created page with "ルミステロール"

New page

<languages />
<div lang="en" dir="ltr" class="mw-content-ltr">
{{chembox
| Watchedfields = changed
| verifiedrevid = 408754551
| Name = Lumisterol
| ImageFile = Lumisterol.svg
| ImageSize = 200px
| ImageName = Lumisterol
| IUPACName = (22''E'')-9β,10α-Ergosta-5,7,22-trien-3β-ol
| SystematicName = (1''R'',3a''R'',7''S'',9a''S'',9b''R'',11a''R'')-1-[(2''R'',3''E'',5''R'')-5,6-Dimethylhept-3-en-2-yl]-9a,11a-dimethyl-2,3,3a,6,7,8,9,9a,9b,10,11,11a-dodecahydro-1''H''-cyclopenta[''a'']phenanthren-7-ol
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 4941479
| InChI = 1/C28H44O/c1-18(2)19(3)7-8-20(4)24-11-12-25-23-10-9-21-17-22(29)13-15-27(21,5)26(23)14-16-28(24,25)6/h7-10,18-20,22,24-26,29H,11-17H2,1-6H3/b8-7+/t19-,20+,22-,24+,25-,26+,27+,28+/m0/s1
| InChIKey = DNVPQKQSNYMLRS-YAPGYIAOBK
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C28H44O/c1-18(2)19(3)7-8-20(4)24-11-12-25-23-10-9-21-17-22(29)13-15-27(21,5)26(23)14-16-28(24,25)6/h7-10,18-20,22,24-26,29H,11-17H2,1-6H3/b8-7+/t19-,20+,22-,24+,25-,26+,27+,28+/m0/s1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = DNVPQKQSNYMLRS-YAPGYIAOSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 474-69-1
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 170D11Q82N
| PubChem = 6436872
| SMILES = O[C@@H]4C/C3=C/C=C1\[C@@H](CC[C@]2([C@H]1CC[C@@H]2[C@@H](/C=C/[C@H](C)C(C)C)C)C)[C@]3(C)CC4
}}
|Section2={{Chembox Properties
| C=28 | H=44 | O=1
}}
}}
</div>

<div lang="en" dir="ltr" class="mw-content-ltr">
'''Lumisterol''' is a compound that is part of the [[vitamin D]] family of [[steroid]] compounds. It is the (9β,10α) [[stereoisomer]] of [[ergosterol]] and was produced as a photochemical by-product in the preparation of vitamin D<sub>1</sub>, which was a mixture of [[Ergocalciferol|vitamin D<sub>2</sub>]] and lumisterol. Vitamin D<sub>2</sub> can be formed from lumisterol by an electrocyclic ring opening and subsequent [[Sigmatropic reaction#.5B1.2C7.5D_Shifts|sigmatropic [1,7] hydride shift]].

Lumisterol has an analog based on [[7-dehydrocholesterol]], known as lumisterol 3.
</div>

<div lang="en" dir="ltr" class="mw-content-ltr">
{{二次利用|date=4 May 2023}}
[[Category:Vitamin D]]
[[Category:Sterols]]
</div>